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The S-Block Elements

Question
CBSEENCH11007164

What is Gypsum? How is it prepared? What are its properties and uses?

Solution
Gypsum is hydrated calcium sulphate, CaSO4.2H2O
Preparation: It can be prepared by the action of dilute sulphuric acid on calcium carbonate or calcium hydroxide.
CaCO subscript 3 left parenthesis straight s right parenthesis space plus space straight H subscript 2 SO subscript 4 left parenthesis aq right parenthesis space space rightwards arrow space space CaSO subscript 4 left parenthesis straight s right parenthesis space plus space CO subscript 2 left parenthesis straight g right parenthesis space plus space straight H subscript 2 straight O left parenthesis straight l right parenthesis
Ca left parenthesis OH right parenthesis subscript 2 left parenthesis aq right parenthesis space plus space straight H subscript 2 SO subscript 4 left parenthesis aq right parenthesis space rightwards arrow space space space CaSO subscript 4 left parenthesis straight s right parenthesis space plus space 2 straight H subscript 2 straight O left parenthesis straight l right parenthesis
Properties:
(i) It is a white crystalline solid sparingly soluble in water.
(ii) On heating to 393 K, it changes into CaSO subscript 4. space 1 half straight H subscript 2 straight O left parenthesis Plaster space of space Paris right parenthesis. 
On heating to about 437 K, it changes into anhydrous calcium sulphate. 

                        stack CaSO subscript 4. space 2 straight H subscript 2 straight O with Gypsum below space rightwards arrow with 390 on top stack space CaSO subscript 4.1 half straight H subscript 2 straight O with Plaster space of space Paris below space space rightwards arrow from 473 straight K to Above of space CaSO subscript 4
 
Uses. It is used: 
(i) in the manufacture of cement. 
(ii) for manufacturing Plaster of Paris
(iii) as a drying agent. 
(iv) for the preparation of ammonia, bleaching powder slaked lime and basic calcium nitrate.