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The S-Block Elements

Question
CBSEENCH11007142

Comment on each of the following observations:
straight E to the power of circled dash space for space straight M to the power of 2 plus end exponent left parenthesis aq right parenthesis space plus 2 straight e to the power of minus space space rightwards arrow space space straight M left parenthesis straight s right parenthesis.
  (where M = Ca,  Sr or Ba) is nearly constant.

Solution
straight E to the power of circled dash space of space any space straight M to the power of 2 plus end exponent vertical line space straight M space electrode space depends space upon space three space factors colon(i) Ionisation enthalpy
(ii) Enthalpy of hydration
(iii) Enthalpy of vaporisation
The combined effect of these factors is approximately the same for Ca, Sr, and Ba. Hence, their electrode potentials are nearly constant.