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The S-Block Elements

Question
CBSEENCH11007095

How will you explain the reactivity of alkali metals with halogens ?

Solution

Alkali metals combine with halogens to form metal halides, which are ionic crystalline solids having general formula M+X.
2 straight M plus straight X subscript 2 space rightwards arrow space 2 straight M to the power of plus straight X to the power of minus
Reactivity of alkali metals with particular halogen increases from Li to Cs. On the other hand, the reactivity of halogens with particular alkali metal M decreases from F2 to I2.

All the halides of alkali metals except lithium fluoride are freely soluble in water. The low solubility of lithium fluoride is attributed to the greater force of attraction between lithium ions and fluoride ions in the crystal lattice.