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The S-Block Elements

Question
CBSEENCH11007093

How would you explain that the following observations?
LiI is more soluble than KI in ethanol?

Solution

As the size of Li+ ion is much smaller than K+ ion, therefore Li+ ion can polarise bigger I- ions to a greater extent than K+ ions (Fajan rule). As a result, LiI is more covalent than KI and hence is more soluble in ethanol. (organic solvent).