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The S-Block Elements

Question
CBSEENCH11007085

Comment on each of the following observations:
 The mobilities of the alkali metal ions in aqueous solution are Li+ < Na+ < K+ < Rb< Cs+

Solution
We know that smaller the size of the ion, more highly it is hydrated and thus greater is the mass of the hydrated ion and hence smaller is the ionic mobility. Since the extent of hydration of the ion decreases in the order
Li+ > Na+ > K+ > Rb+ > Cstherefore, ionic mobility increases in the order Li+ < Na+ < K+ < Rb+ < Cs+.