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The S-Block Elements

Question
CBSEENCH11007083

Why ionic conductance of alkali metal ions in aqueous solution are in the order:
Li+ < Mg + < K+ < Rb+ < Cs+ Explain ?

Solution
Smaller the ion, greater is the degree of hydration and hence lesser is the ionic mobility. Since Li+ ion has the maximum degree of hydration so it has lowest ionic mobility. Since the degree of hydration decreases from Li+ to Cs+, therefore, ionic conductance increases from Li+ to Cs+.