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The S-Block Elements

Question
CBSEENCH11007069

The ionic radii of alkali metal ions in aqueous solution follows the order Li+ > Na+> K+ > Rb+ > CsJustify the above order.

Solution
The alkali metal ions get extensively hydrated in aqueous solutions. Smaller is the size of the ion more is the extent or degree of hydration. Thus, as a matter of fact, the ionic radii in water decrease from Li+ to Cs+ i.e. the ion which should have been the smallest is actually the largest in size in water.