NEET chemistry

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Question
CBSEENCH11008322

A gas such as carbon monoxide would be most likely to obey the ideal gas law at

  • high temperatures and low pressures

  • low temperatures and high pressures

  • high temperatures and high pressures

  • low temperatures and low pressures

Solution

A.

high temperatures and low pressures

Real gases show ideal gas behaviour at high temperatures and low pressures.
 
PV = nRT

Sponsor Area

Question
CBSEENCH11008323

If Avogadro number NA, changed from 6.022 x 1023 mol-1 this would change

  • the definition of mass in units of grams

  • the mass of one mole of carbon

  • the ratio of chemical species to each other in the balanced equation

  • the ratio of elements to each other in a compound

Solution

B.

the mass of one mole of carbon

If Avogadro number NA, is changed from 6.022 x 1023 mol-1 to 6.022 x 1020 mol-1 this would change the mass of one mole of carbon.
therefore,
1 mole of carbon has mass = 12 g
or 6.022 x 1023 atoms of carbon have mass = 12 g 
therefore, 6.022 x 1020 atoms of carbon have mass

fraction numerator 12 over denominator 6.022 space straight x space 10 to the power of 23 end fraction space x space 6.022 space x space 10 to the power of 20 space equals space 0.012 g

Question
CBSEENCH11008324

What is the pH of the resulting solution when equal volumes of 0.1 M NaOH and 0.01 M HCl are mixed?

  • 12.65

  • 2.0

  • 7.0

  • 1.04

Solution

A.

12.65

When equal volumes of acid and base are mixed then resulting solution become alkaline if the concentration of base is taken high.
Let normality  of the solution after mixing 0.1 M
NaOH and 0.01 M HCl is N.
therefore,   N1V1 - N2V2 = NV
or   0.1 x 1 - 0.01 x 1 = N x 2
Since normality, of NaOH, is more than that of HCl. Hence, the resulting solution is alkaline.
Or
[OH-] = N = 0.09/2 = 0.045 N
Or pOH = - log (0.045) = 1.35
therefore, pH = 14-pOH
= 14 - 1.35 = 12.65

Question
CBSEENCH11008325

Decreasing order of stability of straight O subscript 2 comma space straight O subscript 2 superscript minus comma space straight O subscript 2 superscript plus comma space and space straight O subscript 2 superscript 2 minus end superscript is

  • straight O subscript 2 superscript plus space greater than space straight O subscript 2 space greater than space straight O subscript 2 superscript minus space greater than space straight O subscript 2 superscript 2 minus end superscript
  • straight O subscript 2 superscript 2 minus end superscript space greater than space straight O subscript 2 superscript minus space greater than space straight O subscript 2 space greater than space straight O subscript 2 superscript plus
  • straight O subscript 2 space greater than straight O subscript 2 superscript plus space greater than space straight O subscript 2 superscript 2 minus end superscript space greater than thin space straight O subscript 2 superscript minus
  • straight O subscript 2 superscript minus space greater than thin space straight O subscript 2 superscript 2 minus end superscript space greater than thin space straight O subscript 2 superscript plus space greater than thin space straight O subscript 2

Solution

A.

straight O subscript 2 superscript plus space greater than space straight O subscript 2 space greater than space straight O subscript 2 superscript minus space greater than space straight O subscript 2 superscript 2 minus end superscript

order of stability directly proportional to the bond order
therefore, the order of the stability of given species,
stack space space with Bond space order below space space space stack straight O subscript 2 superscript plus with 2.5 below space greater than stack space straight O subscript 2 space with 2 below greater than stack space straight O subscript 2 superscript minus with 1.5 below space greater than space stack straight O subscript 2 superscript 2 minus end superscript with 1 below

Question
CBSEENCH11008327

Which one of the following pairs of the solution is not an acidic buffer?

  • HClO4 and NaClO4

  • CH3COOH and CH3COONa

  • H2CO3 and Na2PO4

  • H2PO4 and Na3PO4

Solution

A.

HClO4 and NaClO4

A buffer solution is one which resists changes in pH when small quantities of an acid or an alkali are added to it.

HClO4 and NaClO4 are not an acidic buffer because strong acid with its salt cannot form buffer solution.