NEET chemistry

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Question
CBSEENCH11008252

The value of Planck's constant is 6.63 x 10-34 Js. The speed of light is 3 x1017 nms-1 . Which value is closet to the wavelength in nanometer of a quantum of light with frequency of 6 x 1015 s-1 ?

  • 10

  • 25

  • 50

  • 75

Solution

C.

50

Given, Planck's constant,
h= 6.63 x10-34
speed of light, c= 3 x1017 nms-1 
Frequency of quanta
v=6 x1015 s-1
Wavelength, λ =?
We know that,
straight v equals straight c over straight lambda

straight lambda space equals straight c over straight v
equals fraction numerator 3 straight x 10 to the power of 17 over denominator 6 space straight x space 10 to the power of 15 end fraction space equals space 0.5 space straight x space 10 squared space nm space equals space 50 space nm

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Question
CBSEENCH11008253

What is the maximum number of electrons that can be associated with the following set of quantum number?
n=3, l =1 and m=-1.

  • 10

  • 6

  • 4

  • 2

Solution

D.

2

The orbital of the electron having =3, l =1 and m= -1 is 3pz (as nlm) and an orbital can have a maximum of two electrons with opposite spins.
therefore, 3pz orbital contains only two electrons or only 2 electrons are associated with n=3, l=1, m=-1.

Question
CBSEENCH11008255

Based on equation
E=-2.178 x 10-18open parentheses straight Z squared over straight n squared close parentheses certain conclusions are written. Which of them is not correct?

  • The negative sign in the equation simply means that the energy of an electron bound to the nucleus is lower than if would be if the electrons were at the infinite distance from the nucleus.

  • Larger the value of n, the larger is the orbit radius

  • Equation can be used to calculate the change in energy when the electron changes orbit

  • For n=1 the electron has a more negative energy than it does for n=6 which means that the electron is more loosely bound in the smallest allowed orbit.

Solution

D.

For n=1 the electron has a more negative energy than it does for n=6 which means that the electron is more loosely bound in the smallest allowed orbit.

If n=1,
E1 = - 2.178 x 10-18 Z2 J
If n=6
space straight E subscript 6 end subscript space equals space fraction numerator negative 2.178 space straight x space 10 to the power of negative 18 end exponent over denominator 36 end fraction

equals space 6.05 space straight x space 10 to the power of negative 20 end exponent space straight Z squared space straight J
From the above calculation, it is obvious that electron has a more negative energy than it does for n=6. it means that electron is more strongly bound in the smallest allowed orbit.

Question
CBSEENCH11008256

How many grams of the concentrated nitric solution should be used to prepare 250 mL o 2.0M HNO3 ? The concentrated acid is 70% HNO3.

  • 45.0 g conc. HNO3

  • 90.0 g conc. HNO3

  • 70.0 g conc. HNO3

  • 54.0 g conc. HNO3

Solution

A.

45.0 g conc. HNO3

Given, molarity of solution = 2
Volume of solution = 250 mL = 250/1000 = 1/4 L
Molar mass of 
HNO3 = 1+14+3 x 16 = 63 g mol-1
therefore, Molarity
fraction numerator weight space of space HNO subscript 3 over denominator mass space of space HNO subscript 3 space straight x space volume space of space solution space left parenthesis straight L right parenthesis end fraction
therefore comma
Weight space of space HNO subscript 3 space equals space molarity space straight x space space mol. mass space straight x space volume space left parenthesis straight l right parenthesis

equals 2 space straight x space 63 space straight x space 1 fourth straight g space equals space 31.5 space straight g
It space is space the space weight space of space 100 percent sign space HNO subscript 3
But space the space given space acid space is space 70 percent sign space HNO subscript 3

therefore comma
its space weight space equals space 31.5 space straight x space 100 over 70 space straight g space equals space 45 space straight g

Question
CBSEENCH11008257

Dipole-induced dipole interactions are present in which of the following pair?

  • H2O and alcohol

  • Cl2 and CCl4

  • HCl and He atoms

  • SiF4 and He atoms

Solution

C.

HCl and He atoms

Dipole-induced dipole interaction is present in the pair in which the first species is polar and the other is non-polar.
H2O and alcohol both are non-polar so there exist dipole-dipole interactions in between them.
Cl2 and CCl4 both are non-polar so there exists induced dipole -induced dipole interactions in between them. Similarly is true for SiCl4 and He atoms pair.

HCl is a polar molecule, whereas He atoms are non-polar, so in between them dipole-induced dipole interactions exist.