NEET chemistry

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Question
CBSEENCH11008422

Calculate the pOH of a solution at 250C that contains 1 x 10-10 M of hydronium ions.

  • 7

  • 4

  • 9

  • 1

Solution

B.

4

[H3O+] = [H+] = 10-10

pH + pOH = [14]
pH = - log [ H+]
pH = - log [10-10]
pH = 10
⇒ pOH + 10 = 14
⇒ pOH = 14-10 = 4

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Question
CBSEENCH11008424

A Weak acid, HA has a Ka of 1.00 x 10-5. If 0.100 mole of this percentage of acid dissociated at equilibrium is closest to:

  • 99.0%

  • 1.00%

  • 99.9 %

  • 0.100%

Solution

B.

1.00%

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Question
CBSEENCH11008425

Which of the following oxidation states are the most characteristics for lead and tin respectively? 

  • +4,+2

  • +2,+4

  • +4,+4

  • +2,+2

Solution

B.

+2,+4

The tendency to form +2 ionic state increase on moving down the group due to the inert pair effect.
Most characteristic oxidation state for lead and tin are +2,+4 respectively.

Question
CBSEENCH11008426

The correct order of C-O bond length among CO, CO32-, CO2 is,

  • CO2<  CO32-<  CO

  • CO <  CO32-<  CO2

  • CO32- <CO2 <CO

  • CO < CO2 < CO32-

Solution

B.

CO <  CO32-<  CO2

The bond length is the average distance between the centres of nuclei of two bonded atoms. Centres of nuclei of two bonded atoms. A multiple bonds (double or triple bond) is always shorter than the corresponding single bond. 
The C- atom is CO32- is sp2 hybridised as shown
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The C- atom is CO2 is sp hybridised with a bond distance of carbon -oxygen is 122 pm.
straight O equals straight C equals straight O space left right arrow space to the power of plus straight O space identical to space straight C minus straight O to the power of minus space left right arrow space straight O to the power of minus minus straight C identical to straight O to the power of plus
The C- atom in CO is sp hybridised with C-O bond distance is 110 pm:
So the correct order is 
CO <  CO32-<  CO2

Question
CBSEENCH11008427

The following equilibrium constants are given:

N2 + 3H2  ⇌ 2NH3; K1

N2 +O2  ⇌ 2NO; K2

H2 + 1/2O2  ⇌ H2O' K3

The equilibrium constants for the oxidation of NH3 by oxygen to give NO is:

  • K2K33 /K1

  • KK2K32 /K1

  • K22K3 /K1

  • K1K2 /K3

Solution

A.

K2K33 /K1

The required equation for the oxidation of NH3 by oxygen to give NO is:
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