JEE chemistry

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Question
CBSEENCH11008108

Δ U is equal to

  • Isochoric work

  • Isobaric work

  • Adiabatic work

  • Isothermal work

Solution

C.

Adiabatic work

From 1st law thermodynamics:
ΔU = q + w
For adiabatic process :
q = 0
∴ ΔU = w
∴ Work involves in the adiabatic process is at the expense of a change in internal energy of the system.

Sponsor Area

Question
CBSEENCH11008109

The radius of the second Bohr orbit for the hydrogen atom is :
(Plank's const. h = 6.6262 × 10–34 Js ; mass of electron = 9.1091 × 10–31 kg ; charge of electron
e = 1.60210 × 10–19 C ; permittivity of vacuum
∈0 = 8.854185 × 10–12 kg–1 m–3 A2)

  • 1.65Å

  • 4.76Å

  • 0.529Å

  • 2.12Å

Solution

D.

2.12Å

Radius of nth Bohr orbit in H-atom = 0.53 n2Å
Radius of II Bohr orbit = 0.53 ×(2)2 = 2.12 Å

Question
CBSEENCH11008110

pKa of a weak acid (HA) and pKb of a weak base (BOH) are 3.2 and 3.4, respectively. The pH of their salt (AB) solution is

  • 7.2

  • 6.9

  • 7.0

  • 1.0

Solution

B.

6.9

Given
pKa (HA) = 3.2
pKb (BOH) = 3.4
As given salt is of weak acid and weak base
therefore,
pH = 7 + (1/2)pKa - (1/2)pKb
= 7 + (1/2)(3.2) - (1/2)(3.4)
= 6.9

Question
CBSEENCH11008111

The most abundant element by mass in the body of a healthy human adult are :
Oxygen (61.4%) ; Carbon (22.9%), Hydrogen(10.0%) ; and Nitrogen (2.6%). The weight which a 75 kg person would gain if all 1H atoms are replaced by 2H atoms is

  • 15 kg

  • 37.5 Kg

  • 7.5 Kg

  • 40 Kg

Solution

C.

7.5 Kg

Mass in the body of a healthy human adult has :-
Oxygen = 61.4%, Carbon = 22.9%,
Hydrogen = 10.0% and Nitrogen = 2.6%
Total weight of person = 75 kg
Mass due to 1H is =
(10/100)x 75 = 7.5kg
1H atoms are replaced by 2H atoms.
So mass gain by person =7.5 kg

Question
CBSEENCH11008112

In the following reactions, ZnO is respectively acting as a/an :
(a) ZnO + Na2O → Na2ZnO2
(b) ZnO + CO2 → ZnCO3

  • base and acid

  • base and base

  • acid and acid

  • acid and base

Solution

D.

acid and base

ZnO is amphoteric oxide,in given reaction,
(a) ZnO + Na2O → Na2ZnO2
In this reaction ZnO act as Acid.
(b) ZnO + CO2 → ZnCO3
In this reaction ZnO act as Base.