Haloalkanes And Haloarenes

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Question
CBSEENCH12011348

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A ( Predominantly) is
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Solution

B.

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The mechanism of electrophilic addition reaction is consistent with the occurrence of rearrangement leading to more stable carbocation.
The order of stability of carbocation is as;
T > S> P > CH3
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Question
CBSEENCH12011258

2,3 -dimethyl - 2- butene can be prepared by heating which of the following compounds with a strong acid?

  • (CH3)2CH-CH(CH)3-CH=CH2

  • (CH3)3C-CH=CH2

  • (CH3)2C =CH-CH2-CH3

  • (CH3)2CH-CH2-CH=CH2

Solution

B.

(CH3)3C-CH=CH2

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Question
CBSEENCH12011084

A single compound of the structure is

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obtainable from ozonolysis of which of the following cyclic compound?

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Solution

A.

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Question
CBSEENCH12011325

Benzene reacts with CH3Cl in the presence of anhydrous AlCl3 to form

  • toluene

  • chlorobenzene

  • benzylchloride

  • xylene

Solution

A.

toluene

CH3Cl in the presence of anhydrous AlCl3 acts as alkylation agent and introduces an alkyl group.

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This reaction is known as Friedel-Craft's alkylation of benzene.

Question
CBSEENCH12011381

Consider the following compounds:

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The correct decreasing order of their reactivity towards hydrolysis is;

  • (ii) >(iv) > (iii) > (i)

  • (i) > (ii) > (iii) > (iv)

  • (iv) > (ii) > (i) > (iii)

  • (ii)  > (iv)> (i) > (iii) 

Solution

D.

(ii)  > (iv)> (i) > (iii) 

Decreasing order of their reactivity toward hydrolysis is:
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