The Periodic Table

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Question
ICSEENICH9010096

What is the need for classification of elements?

Solution

It is impossible for a chemist to study all the elements and their compounds. Hence, classification is a must.

Following are the reasons for the classification of elements:

  1. To study elements better
  2. To correlate the properties of the elements with some fundamental properties which are characteristic of all the elements
  3. To reveal relationships between elements 

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Question
ICSEENICH9010097

What was the basis of the earliest attempts made for classification and grouping of elements?

Solution

The first classification of elements was into 2 groups-metals and non-metals.

Question
ICSEENICH9010098

A, B and C are the elements of a Dobereiner's triad. If the atomic mass of A is 7 and that of C is 39, what should be the atomic mass of B?

Solution

At. wt. of A = 7, At. wt. of C = 39

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At. wt. of B = 23

i.e. Average of weights of A and C.

Question
ICSEENICH9010099

Why was Dobereiner's triad discarded?

Solution

  1. Döbereiner failed to arrange all the known elements in the form of triads.
  2. In the triad of fluorine (19), chlorine (35.5) and bromine (80), it is observed that the mean of the atomic masses of fluorine and bromine is ½(19 + 80) = 49.5, not 35.5.