Relative Molecular Mass And Mole

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Question
ICSEENICH12028855

Define cryoscopic constant.

Solution

Cryoscopic constant is defined as the Molal depression constant Or it may be defined as the depression in freezing point when one mole of non-volatile solute is dissolved in one kilogram of solvent. Its units  K Kg mol-1

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Question
ICSEENICH12028856

Match the following: 

 

 

 

A. Colligative property (i)  Polysaccharide
B. Nicol prism (ii) Aldol condensation
C.  Activation energy (iii)  Ammonia
D. Starch   (iv) Polarimeter
E. Acetaldehyde (v) Arrhenius equation

Solution

A.

Colligative property

(i)

 Ammonia

B.

Nicol prism

(ii)

Polarimeter

C.

 Activation energy

(iii)

Arrhenius equation

D.

Starch  

(iv)

 Polysaccharide

E.

Acetaldehyde

(v)

Aldol condensation

Question
ICSEENICH12028857

Ethylene glycol is used as an antifreeze agent. Calculate the amount of ethylene glycol to be added to 4 kg of water of prevent it from freezing at -6°C. (Kfor H20 = 1.85 K mole-1 kg) 

Solution

W =?
W = 4Kg =4000 gm
Kf =1.85
Freezing point of pure water =00 C

increment straight T subscript straight f space equals space 0 minus left parenthesis negative 6 right parenthesis space equals space 0 plus 6 space equals 6 degree space straight C

Molecular space Mass
CH subscript 2 OH
vertical line
CH subscript 2 OH space space space equals 62

straight W subscript 1 space equals space fraction numerator increment straight T subscript straight f space straight x space straight M space straight x space straight W subscript 2 over denominator 1000 space straight x space 1.85 end fraction

straight W subscript 1 space equals fraction numerator space 62 space straight x space 4000 straight x space 6 over denominator 1000 space straight x space 1.85 end fraction space equals 804.32 space gm

Question
ICSEENICH12028858

The freezing point of a solution containing 0.3 gms of acetic acid in 30 gms of benzene is lowered by 0.45K. Calculate the Van’t Hoff factor. (at. wt. of C = 12, H = 1, 0 =16, Kf for benzene = 5.12K kg mole-1)

Solution

increment straight T subscript straight f space equals space straight i space straight x space straight K subscript straight f space straight x space straight m space............1

where space straight m space can space be space

straight m space equals space fraction numerator 1000 space straight x space straight w over denominator straight M space straight x space straight W end fraction

Putting space value space of space straight m space in space equation space 1

straight i space equals space fraction numerator increment straight T subscript straight f space straight x space straight M space straight x space straight W over denominator 1000 space straight x space straight K subscript straight f space straight x space straight w end fraction

space equals fraction numerator 0.45 space straight x space 60 space straight x space 30 space over denominator 1000 straight x space 5.12 space straight x space 0.3 end fraction space equals space.527 space