Cyanides, Isocyanides, Nitro compounds And Amines

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Question
ICSEENICH12028878

(i) Name the type of isomerism exhibited by the following pairs of compounds.

(1) (C2H5)2NH and CH3-NH-C3H7.

(2) 1-butanol and 2 methyl-1-propanol.

(ii) Name the type of isomerism that the compound with molecular formula C3H602 exhibits. Represent the isomers.

Solution

(i)
1. Metamerism
   
2. Chain Isomerism
ii) Functional Isomerism

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Question
ICSEENICH12028881

Acetamide is amphoteric in nature. Give two equations to support this statement.

Solution

Basic nature of acetamide: It reacts with acids and form salts e.g.

Acidic nature of acetamide: It liberates hydrogen gas when treated with reactive metals.


Question
ICSEENICH12028890

Write the formula of the product formed when formaldehyde reacts with ammonia and name the product.

Solution

When formaldehyde reacts with ammonia it forms urotropine.

Question
ICSEENICH12028920

(i) Identify the products A, B and C:

(ii) Identify the reagents X, Y and Z.

straight C subscript 2 straight H subscript 5 Cl space rightwards arrow with straight X on top space straight C subscript 2 straight H subscript 5 CN space rightwards arrow with straight Y on top space straight C subscript 2 straight H subscript 5 CH subscript 2 NH subscript 2 space rightwards arrow with straight Z on top space straight C subscript 2 straight H subscript 5 CH subscript 2 NHCOCH subscript 3

Solution

i) A → Benzoic acid, B → Benzene, C → 3, 5 dichloro benzoic acid


ii) X --> KCN (alc.) Y --> LiAlH4 Z---> CH3COCl