Organic Chemistry – Some Basic Principles and Techniques

Question
CBSEENCH11007481

What do you mean by nomenclature of aliphatic hydrocarbons?

Solution

The commonly adopted systems for naming organic compounds are:
(i) Common or Trivial system: In this system, the name of the organic compound is based on its origin/ history or some property. Though common names are short and easy to remember, yet a particular compound may be given a number of names. e.g. methyl alcohol is named wood-spirit because it is obtained by destructive distillation of wood.
2. IUPAC system: This is the best system for naming the aliphatic organic compounds. To evolve a systematic method of nomenclature, the international group of chemists have several conferences and recommended the most definite set of organic nomenclature rules called International Union of Pure and Applied Chemistry rules (IUPAC rules). In the IUPAC system, name of organic compound consists of three parts:
(i) Word root       (ii) Prefix            (iii) Suffix.

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Question
CBSEENCH11007482

Explain the following with suitable examples:
(i) Word root   (ii) Prefix        (iii) Suffix

Solution

(i) Word root:The word root represents the number of the carbon atoms present in the chain. Depending upon the number of carbons in the longest chain, the compound is assigned a word root as:

Chain length

Word root

Chain length

Word root

C1

Meth

C6

Hex

C2

Eth

C7

Hept

C3

Prop

C8

Oct

C4

But

C9

Non

C5

Pent

C10

Dec

 

(ii) Prefix. There are many groups (called substituents) which are not regarded as functional groups in the IUPAC names of a compound. These are called prefixes. These are put before the word root. Some of the prefixes are given below:

(iii) Suffix: The word root is linked to suffix which may be primary followed by secondary.
(a) Primary suffix: A primary suffix is added after the word root to indicate the nature of carhon-carhon bonds. These are piven below:

Nature of bond

Primary suffix

General name

C–C single bond

–ane

Alkane

C = C double bond

–ene

Alkene

C≡ C triple bond

–yne

Alkyne

(b) Secondary suffix: A secondary suffix is added after the primary suffix to indicate the nature of the functional group. These are given below:

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Question
CBSEENCH11007483

How do you write the IUPAC name of a given organic compound?

Solution

A complete IUPAC name of an organic compound may be represented as:
Prefix + Word root + Primary suffix + Secondary suffix
For example, the complete IUPAC name of the compound


(i) Prefix: Bromo
(ii) Word root: Pent
(iii) Primary suffix: yne
(iv) Secondary suffix: oic acid
∴   Complete name of the compound is 4- Bromopent-2 yne-1-oic acid.
Here 4, 2 and 1 represent the positions of prefix, primary suffix and of the secondary suffix in the carbon atom chain.

Question
CBSEENCH11007484

What are alkanes? What is their general formula? Write the IUPAC names and common names of members containing upto ten carbon atoms.

Solution

Alkanes or paraffin are saturated hydrocarbons having C–C and C–H bonds in their molecules. These are represented by the general formula CnH2n+2 where n may have value 1, 2, 3, 4......etc.
There is hardly any difference between IUPAC and common names of the members except that prefix n-(normal or straight chain) is used for common names of alkanes with four or more carbon atoms present in straight chains. The common name of the compound is written in the bracket.
When

n = 1 CH4 Methane (Methane)
n = 2 C2H6 Ethane (Ethane)
n = 3 C3Hg Propane (Propane)
n = 4 C4H10 Butane (n-Butane)
n = 5 C5H12 Pentane (n-Pentane)
n = 6 C6H14 Hexane (n-Hexane)
n = 7 C7H16 Heptane (n-Heptane)
n = 8 C8H18 Octane (n-Octane)
n = 9 C9H20 Nonane (n-Nonane)
n=10 C10H22 Decane (n-Decane)