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Home > Classification Of Elements And Periodicity In Properties

Classification Of Elements And Periodicity In Properties

Question
CBSEENCH11005476
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Define vander Waal’s radius and compare it with covalent radius.

Solution
Long Answer

Vander Waal's radius is defined as one half of the distance between the nuclei of two adjacent atoms belonging to two neighbouring

molecules of an element in the solid state, vander Waal’s radii are determined by X-ray diffraction method.
Comparison of covalent radius and vander Waal’s radius.
vander Waal’s radii are always larger than covalent radii. This is because for the formation of covalent bond, atoms move to come closer to each other due to the overlapping of orbitals.
On the other hand, vander Waal’s forces operating between atoms are weak, therefore, adjacent atoms belonging to two neighbouring molecules are at relatively larger distances. Clearly, one half of internuclear distance between adjacent atoms belonging to two neighbouring molecules will be more than one half of the distance between the nuclei of two like atoms forming a single covalent bond. Consequently, vander Waals’ radii are always larger than covalent radii. For example, covalent radius of chlorine is 99 pm whereas vander Waal’s radius of chlorine is 180 pm.

Some More Questions From Classification of Elements and Periodicity in Properties Chapter

Which property is the basis of long form of periodic table?

How many elements are placed in each period of the p-block?

What is the number of groups in: (i) p-block  (ii) d-block?

How many elements are present in:
(i) second period    
(ii) fourth period    
(iii) sixth period?

What is the name given to the s-block elements?

To which block the element with outer electronic configuration 4s23d10 belongs?

Why are there 10 elements in each series of d-block?

In terms of electronic configuration,
what is common in a given period and group?

Give the general electronic configuration of
(i) Transition elements     (ii) Inner transition elements.

Name the group and period to which an element with Z = 15 belongs ?

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